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Temperature dependent studies of NO recombination to heme and heme proteins

The rebinding kinetics of NO to the heme iron of myoglobin (Mb) is investigated as a function of temperature. Below 200K, the transition state enthalpy barrier associated with the fastest (~10ps) recombination phase is found to be zero, while a slower geminate phase (~200ps) reveals a small enthalpi...

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Main Authors: Ionascu, Dan, Gruia, Flaviu, Ye, Xiong, Yu, Anchi, Rosca, Florin, Beck, Chris, Demidov, Andrey, Olson, John S., Champion, Paul M.
Format: Artigo
Jezik:Inglês
Izdano: 2005
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Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2553725/
https://ncbi.nlm.nih.gov/pubmed/16316238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja054249y
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