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Temperature dependent studies of NO recombination to heme and heme proteins
The rebinding kinetics of NO to the heme iron of myoglobin (Mb) is investigated as a function of temperature. Below 200K, the transition state enthalpy barrier associated with the fastest (~10ps) recombination phase is found to be zero, while a slower geminate phase (~200ps) reveals a small enthalpi...
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| Main Authors: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2553725/ https://ncbi.nlm.nih.gov/pubmed/16316238 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja054249y |
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