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Low Frequency Spectral Density of Ferrous Heme: Perturbations Induced by Axial Ligation and Protein Insertion

Femtosecond coherence spectroscopy is used to probe low frequency (20–400 cm(−1)) modes of the ferrous heme group in solution, with and without 2-methyl imidazole (2MeIm) as an axial ligand. The results are compared to heme proteins (CPO, P450(cam), HRP, Mb) where insertion of the heme into the prot...

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Detalhes bibliográficos
Main Authors: Gruia, Flaviu, Ye, Xiong, Ionascu, Dan, Kubo, Minoru, Champion, Paul M.
Formato: Artigo
Idioma:Inglês
Publicado em: The Biophysical Society 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2098722/
https://ncbi.nlm.nih.gov/pubmed/17766351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1529/biophysj.107.114736
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