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Low Frequency Spectral Density of Ferrous Heme: Perturbations Induced by Axial Ligation and Protein Insertion
Femtosecond coherence spectroscopy is used to probe low frequency (20–400 cm(−1)) modes of the ferrous heme group in solution, with and without 2-methyl imidazole (2MeIm) as an axial ligand. The results are compared to heme proteins (CPO, P450(cam), HRP, Mb) where insertion of the heme into the prot...
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| Autores principales: | , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
The Biophysical Society
2007
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2098722/ https://ncbi.nlm.nih.gov/pubmed/17766351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1529/biophysj.107.114736 |
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