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Do the Terms “%ee” and “%de” Make Sense as Expressions of Stereoisomer Composition or Stereoselectivity?

Enantiomeric excess (ee) was originally defined as a term to describe enantiomeric composition, and was equated with optical purity. More recently, ee and its cousin de (diastereomeric excess) have been used (inappropriately) to quantitate stereoselectivity. The quantity ee has been used in equation...

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Bibliographic Details
Main Author: Gawley, Robert E.
Format: Artigo
Language:Inglês
Published: 2006
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2536600/
https://ncbi.nlm.nih.gov/pubmed/16526791
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052554w
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