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Do the Terms “%ee” and “%de” Make Sense as Expressions of Stereoisomer Composition or Stereoselectivity?
Enantiomeric excess (ee) was originally defined as a term to describe enantiomeric composition, and was equated with optical purity. More recently, ee and its cousin de (diastereomeric excess) have been used (inappropriately) to quantitate stereoselectivity. The quantity ee has been used in equation...
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| Format: | Artigo |
| Jezik: | Inglês |
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2006
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| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2536600/ https://ncbi.nlm.nih.gov/pubmed/16526791 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052554w |
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