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Polyketide Double Bond Biosynthesis. Mechanistic Analysis of the Dehydratase-Containing Module 2 of the Picromycin/Methymycin Polyketide Synthase

Picromycin/methymycin synthase (PICS) is a modular polyketide synthase (PKS) that is responsible for the biosynthesis of both 10-deoxymethynolide (1) and narbonolide (2), the parent 12- and 14-membered aglycone precursors of the macrolide antibiotics methymycin and picromycin, respectively. PICS mod...

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Detalhes bibliográficos
Main Authors: Wu, Jiaquan, Zaleski, Toby J., Valenzano, Chiara, Khosla, Chaitan, Cane, David E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533740/
https://ncbi.nlm.nih.gov/pubmed/16332089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja055672+
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