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Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones

[Image: see text] The first example of Pd-catalyzed asymmetric allyl alkylation of the conformationally non-rigid acyclic ketone enolates is reported with excellent yields, regioselectivity and enantioselectivity. The double bond geometry of the allyl enol carbonates affects its reactivity, selectiv...

詳細記述

保存先:
書誌詳細
主要な著者: Trost, Barry M., Xu, Jiayi
フォーマット: Artigo
言語:Inglês
出版事項: 2005
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533158/
https://ncbi.nlm.nih.gov/pubmed/16332054
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja055968f
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