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Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
[Image: see text] The first example of Pd-catalyzed asymmetric allyl alkylation of the conformationally non-rigid acyclic ketone enolates is reported with excellent yields, regioselectivity and enantioselectivity. The double bond geometry of the allyl enol carbonates affects its reactivity, selectiv...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2005
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533158/ https://ncbi.nlm.nih.gov/pubmed/16332054 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja055968f |
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