Sulfur K-edge XAS and DFT calculations on superoxide reductase: Role of the axial thiolate in reactivity

Superoxide reductase (SOR) is a non-heme iron enzyme which reduces superoxide to peroxide at a diffusion-controlled rate. Sulfur K-edge x-ray absorption spectroscopy (XAS) is used to investigate the ground state electronic structure of the resting high-spin and CN(−) bound low-spin Fe(III) forms of...

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Main Authors: Dey, Abhishek, Jenney, Francis E., Adams, Michael W. W., Johnson, Michael K., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado: 2007
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533108/
https://ncbi.nlm.nih.gov/pubmed/17887751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064167p
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