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Sulfur K-edge XAS and DFT calculations on superoxide reductase: Role of the axial thiolate in reactivity
Superoxide reductase (SOR) is a non-heme iron enzyme which reduces superoxide to peroxide at a diffusion-controlled rate. Sulfur K-edge x-ray absorption spectroscopy (XAS) is used to investigate the ground state electronic structure of the resting high-spin and CN(−) bound low-spin Fe(III) forms of...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , , , , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2007
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533108/ https://ncbi.nlm.nih.gov/pubmed/17887751 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064167p |
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