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Remote Control of Diastereoselectivity in Intramolecular Reactions of Chiral Allylsilanes
During investigations of cyclization reactions between chiral allylsilanes and N-acyliminium ions, it was discovered that a suitably positioned benzyloxy group on the allylsilane component caused a reversal in the diastereoselectivity of these reactions relative to that normally observed with alkyl-...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2519900/ https://ncbi.nlm.nih.gov/pubmed/17044701 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja063411+ |
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