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Diastereoselection in the Formation of Contiguous Quaternary Carbon Stereocenters by the Intramolecular Heck Reaction
The second in a series of two papers, this study examines the origins of diastereoselection in the second ring closure of the highly diastereoselective double Heck cyclization of cyclohexenes 1 and 3 that form contiguous quaternary stereocenters. Seven model substrates were synthesized and cyclized...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2006
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2535793/ https://ncbi.nlm.nih.gov/pubmed/16555810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0523363 |
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