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Diastereoselection in the Formation of Contiguous Quaternary Carbon Stereocenters by the Intramolecular Heck Reaction

The second in a series of two papers, this study examines the origins of diastereoselection in the second ring closure of the highly diastereoselective double Heck cyclization of cyclohexenes 1 and 3 that form contiguous quaternary stereocenters. Seven model substrates were synthesized and cyclized...

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Detalles Bibliográficos
Main Authors: Overman, Larry E., Watson, Donald A.
Formato: Artigo
Idioma:Inglês
Publicado: 2006
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2535793/
https://ncbi.nlm.nih.gov/pubmed/16555810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0523363
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