Use of the Intramolecular Heck Reaction for Forming Congested Quaternary Carbon Stereoenters. Stereocontrolled Total Synthesis of (±)-Gelsemine

Intramolecular Heck reactions of α,β-unsaturated 2-haloanilides derived from azatricyclo[4.4.0.02,8]decanone 5 efficiently install the congested spirooxindole functionality of gelsemine. Depending upon the Heck reaction conditions and the nature of the β-substituent, either products having the natur...

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Detalhes bibliográficos
Main Authors: Madin, Andrew, O’Donnell, Christopher J., Oh, Taeboem, Old, David W., Overman, Larry E., Sharp, Matthew J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2597289/
https://ncbi.nlm.nih.gov/pubmed/16366557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja055711h
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