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Oxonitriles: A Grignard Addition-Acylation Route to Enamides
Sequential addition of three different Grignard reagents and pivaloyl chloride to 3-oxo-1-cyclohexene-1-carbonitrile installs four new bonds to generate a diverse array of cyclic enamides. Remarkably, formation of the C-magnesiated nitrile intermediate is followed by preferential acylation by pivalo...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2518779/ https://ncbi.nlm.nih.gov/pubmed/17020332 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0619765 |
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