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Grignard Reagent-Mediated Conversion of an Acyl Nitroso-Anthracene Cycloadduct to a Nitrone

An intramolecular hetero-Diels-Alder cycloadduct of an acyl nitroso compound and a 9, 10-dimethyl anthracene derivative was prepared as a potential nitroxyl (HNO) donor. This compound did not release HNO under any of the conditions tested. Treatment of this cycloadduct with excess MeMgCl resulted in...

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Detalhes bibliográficos
Main Authors: Chen, Weibin, Day, Cynthia S., King, S. Bruce
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3481167/
https://ncbi.nlm.nih.gov/pubmed/17109552
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0615192
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