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Brønsted acid-mediated opening of nitroso cycloadducts under anhydrous conditions

An unusual bicyclic hydroxamate resulted from C-O bond cleavage of acylnitroso hetero-Diels-Alder cycloadducts when treated with catalytic Brønsted acids under anhydrous conditions. Similarly, the formation of a nitrone was observed using one equivalent of triflic acid.

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Detalhes bibliográficos
Main Authors: Bodnar, Brian S., Miller, Marvin J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2613285/
https://ncbi.nlm.nih.gov/pubmed/20160837
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.11.120
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