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Cyclopropanation of nitroso Diels–Alder cycloadducts and application to the synthesis of a 2’,3’-methano carbocyclic nucleoside
Treatment of nitroso Diels–Alder cycloadducts 1 with diazomethane in the presence of palladium acetate gives synthetically useful exo-6-oxa-7-azatricyclo[3.2.1.02,4]octane derivatives 7 in good to excellent yield. Using this methodology, a conformationally restricted 2’,3’-methano carbocyclic nucleo...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2010
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2894734/ https://ncbi.nlm.nih.gov/pubmed/20607121 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.05.062 |
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