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Stereoselectivity of Intramolecular S(N)′ Cyclizations of Alkyllithium Reagents on Methoxy Alkenes
The cyclization of alkyllithium reagents onto methoxy alkenes has been investigated. The alkyllithium reagent was generated by reductive lithiation of an alkyl nitrile. In an unbiased substrate, a methoxy leaving group attached to a stereogenic secondary carbon atom led to the cyclization product wi...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2006
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2496923/ https://ncbi.nlm.nih.gov/pubmed/16438522 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052166u |
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