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Stereoselectivity of Intramolecular S(N)′ Cyclizations of Alkyllithium Reagents on Methoxy Alkenes
The cyclization of alkyllithium reagents onto methoxy alkenes has been investigated. The alkyllithium reagent was generated by reductive lithiation of an alkyl nitrile. In an unbiased substrate, a methoxy leaving group attached to a stereogenic secondary carbon atom led to the cyclization product wi...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2496923/ https://ncbi.nlm.nih.gov/pubmed/16438522 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052166u |
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