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Cyclization via Carbolithiation of α-Amino Alkyllithium Reagents
[Image: see text] We report a new route to tertiary α-amino stereocenters by sequential alkylation of α-amino nitriles followed by reductive lithiation of the nitrile and cyclization onto an alkene. Reductive lithiation of α-amino nitriles using lithium 4,4′-di-tert-butylbiphenylide (LiDBB) and subs...
Bewaard in:
| Hoofdauteurs: | , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2008
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2718755/ https://ncbi.nlm.nih.gov/pubmed/18700774 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801523r |
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