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Fjord-region Benzo[g]chrysene-11,12-dihydrodiol and Benzo[c]phenanthrene-3,4-dihydrodiol as Substrates for Rat Liver Dihydrodiol Dehydrogenase (AKR1C9): Structural Basis for Stereochemical Preference

This study demonstrates that benzo[g]chrysene-11,12-dihydrodiol (B[g]C-11,12-dihydrodiol) derived from the fjord-region parent hydrocarbon B[g]C is oxidized by rat AKR1C9 with a k(cat)/K(m) 100 times greater than that observed with the commonly studied bay-region benzo[a]pyrene-7,8-dihydrodiol (B[a]...

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Autors principals: Shultz, Carol A., Palackal, Nisha T., Mangal, Dipti, Harvey, Ronald G., Blair, Ian A., Penning, Trevor M.
Format: Artigo
Idioma:Inglês
Publicat: 2008
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2440589/
https://ncbi.nlm.nih.gov/pubmed/18251511
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx7003695
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