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Diiron Dithiolato Carbonyls Related to the H(ox)(CO) State of [FeFe]-Hydrogenase
Oxidation of the electron-rich (E(1/2) = −175 vs Ag/AgCl) ethanedithiolato complex Fe(2)(S(2)C(2)H(4))-(CO)(2)(dppv)(2) (1) under a CO atmosphere yielded [Fe(2)(S(2)C(2)H(4))(μ-CO)(CO)(2)(dppv)(2)](+) ([1(CO)](+)), a model for the H(ox)(CO) state of the [FeFe]-hydrogenases. This complex exists as tw...
Tallennettuna:
| Päätekijät: | , , , , , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2008
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2435217/ https://ncbi.nlm.nih.gov/pubmed/18341276 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja7113008 |
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