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A convenient synthesis of the C-1- phosphonate analogue of UDP-GlcNAc and its evaluation as an inhibitor of O-linked GlcNAc transferase (OGT)

The C-1-phosphonate analogue of UDP-GlcNAc has been synthesized using an α-configured C-1-aldehyde as a key intermediate. Addition of the anion of diethyl phosphate to the aldehyde produced the hydroxyphosphonate. The configuration of this key intermediate was determined by x-ray crystallography. De...

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Detalhes bibliográficos
Main Authors: Hajduch, Jan, Nam, Ghilsoo, Kim, Eun Ju, Fröhlich, Roland, Hanover, John A., Kirk, Kenneth L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2243073/
https://ncbi.nlm.nih.gov/pubmed/18039537
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.carres.2007.10.027
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