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[Fe(III)(SR)(4)](1−) Complexes Can Be Synthesized By the Direct Reaction of Thiolates With FeCl(3)

It is shown that the previously characterized [Fe(III)(SR)(4)](1−) (R= Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4 equiv of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1−) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins....

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Main Authors: Chang, Sechin, Koch, Stephen A.
格式: Artigo
語言:Inglês
出版: 2007
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2128701/
https://ncbi.nlm.nih.gov/pubmed/17723243
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2007.07.004
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