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FeCl(2)-Mediated Rearrangement of Allylic Alcohols
[Image: see text] A mild, one-pot procedure to produce 3-substituted allylic alcohols from α,β-unsaturated ketones is described. The addition of an organolithium nucleophile produces a tertiary allylic alcohol as an intermediate, which undergoes a 1,3-OH-migration assisted by FeCl(2). The proposed m...
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| Udgivet i: | ACS Omega |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical Society
2019
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6648291/ https://ncbi.nlm.nih.gov/pubmed/31459755 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b00163 |
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