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[Fe(III)(SR)(4)](1−) Complexes Can Be Synthesized By the Direct Reaction of Thiolates With FeCl(3)
It is shown that the previously characterized [Fe(III)(SR)(4)](1−) (R= Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4 equiv of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1−) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins....
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2128701/ https://ncbi.nlm.nih.gov/pubmed/17723243 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2007.07.004 |
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