Učitavanje...
A new paradigm for electrostatic catalysis of radical reactions in vitamin B(12) enzymes
The catalytic power of enzymes containing coenzyme B(12) cofactor has been, in some respects, the “last bastion” for the strain hypothesis. The present work explores the origin of this effect by using simulation methods that overcome the sampling difficulties of previous energy minimization studies....
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| Glavni autori: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
2007
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1887576/ https://ncbi.nlm.nih.gov/pubmed/17517615 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0702238104 |
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