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A new paradigm for electrostatic catalysis of radical reactions in vitamin B(12) enzymes

The catalytic power of enzymes containing coenzyme B(12) cofactor has been, in some respects, the “last bastion” for the strain hypothesis. The present work explores the origin of this effect by using simulation methods that overcome the sampling difficulties of previous energy minimization studies....

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Bibliografski detalji
Glavni autori: Sharma, Pankaz K., Chu, Zhen T., Olsson, Mats H. M., Warshel, Arieh
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2007
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC1887576/
https://ncbi.nlm.nih.gov/pubmed/17517615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0702238104
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