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Single-enzyme conversion of FMNH(2) to 5,6-dimethylbenzimidazole, the lower ligand of B(12)
The synthesis of 5,6-dimethylbenzimidazole (DMB), the lower ligand of coenzyme B(12), has remained elusive. We report in vitro and in vivo evidence that the BluB protein of the photosynthetic bacterium Rhodospirillum rubrum is necessary and sufficient for catalysis of the O(2)-dependent conversion o...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2007
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1815282/ https://ncbi.nlm.nih.gov/pubmed/17301238 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609270104 |
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