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The 1′,4′-iminopyrimidine tautomer of thiamin diphosphate is poised for catalysis in asymmetric active centers on enzymes
Thiamin diphosphate, a key coenzyme in sugar metabolism, is comprised of the thiazolium and 4′-aminopyrimidine aromatic rings, but only recently has participation of the 4′-aminopyrimidine moiety in catalysis gained wider acceptance. We report the use of electronic spectroscopy to identify the vario...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
National Academy of Sciences
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1765481/ https://ncbi.nlm.nih.gov/pubmed/17182735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609973104 |
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