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Synthesis with Good Enantiomeric Excess of Both Enantiomers of α-Ketols and Acetolactates by Two Thiamin Diphosphate Dependent Decarboxylases.
In addition to the decarboxylation of 2-oxo acids, thiamin diphosphate (ThDP)-dependent decarboxylases/dehydrogenases can also carry out so-called carboligation reactions, where the central ThDP-bound enamine intermediate reacts with electrophilic substrates. For example, the enzyme yeast pyruvate d...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1702321/ https://ncbi.nlm.nih.gov/pubmed/17083961 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bioorg.2006.09.006 |
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