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Electronic and Nuclear Magnetic Resonance Spectroscopic Features of the 1’4’-Iminopyrimidine Tautomeric form of Thiamin Diphosphate- a Novel Intermediate on Enzymes Requiring this Coenzyme
Appropriate compounds were synthesized to create models for the 1’,4’-imino tautomer of the 4’-aminopyrimidine ring of thiamin diphosphate recently found to exist on the pathway of enzymatic reactions requiring this cofactor (Jordan, F., and Nemeria, N.S. (2005) Bioorganic Chemistry, 33, 190−215). T...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2532840/ https://ncbi.nlm.nih.gov/pubmed/16768448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi060395k |
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