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Linking protein structure and dynamics to catalysis: the role of hydrogen tunnelling
Early studies of enzyme-catalysed hydride transfer reactions indicated kinetic anomalies that were initially interpreted in the context of a ‘tunnelling correction’. An alternate model for tunnelling emerged following studies of the hydrogen atom transfer catalysed by the enzyme soybean lipoxygenase...
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society
2006
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1647309/ https://ncbi.nlm.nih.gov/pubmed/16873120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1870 |
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