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An integrated model for enzyme catalysis emerges from studies of hydrogen tunneling
The origins of the enormous rate accelerations brought about by enzymes are discussed. The focus is on enzymatic C–H activation, which has been shown to take place via tunneling. Four enzyme systems illustrate the impact of site-specific mutagenesis, changes in temperature or changes in protein solv...
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| Hovedforfatter: | |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2846846/ https://ncbi.nlm.nih.gov/pubmed/20354595 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.cplett.2009.01.038 |
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