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Variable character of O—O and M—O bonding in side-on (η(2)) 1:1 metal complexes of O(2)

The structures and the O—O and M—O bonding characters of a series of reported side-on (η(2)) 1:1 metal complexes of O(2) are analyzed by using density functional theory calculations. Comparison of the calculated and experimental systems with respect to O—O bond distance, O—O stretching frequency, an...

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Detalhes bibliográficos
Main Authors: Cramer, Christopher J., Tolman, William B., Theopold, Klaus H., Rheingold, Arnold L.
Formato: Artigo
Idioma:Inglês
Publicado em: The National Academy of Sciences 2003
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC152974/
https://ncbi.nlm.nih.gov/pubmed/12634422
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0535926100
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