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Mixtures of monodentate P-ligands as a means to control the diastereoselectivity in Rh-catalyzed hydrogenation of chiral alkenes

The previously reported concept of using mixtures of monodentate ligands in a combinatorial manner in order to influence enantio- or regioselectivity of transition metal catalyzed processes has been extended to include diastereoselectivity. Accordingly, 1,2- and 1,3-asymmetric induction in the Rh-ca...

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Autori principali: Reetz, Manfred T, Guo, Hongchao
Natura: Artigo
Lingua:Inglês
Pubblicazione: Beilstein-Institut 2005
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC1399451/
https://ncbi.nlm.nih.gov/pubmed/16542016
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1860-5397-1-3
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