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A supramolecularly tunable chiral diphosphine ligand: application to Rh and Ir-catalyzed enantioselective hydrogenation
A supramolecularly tunable chiral bisphosphine ligand bearing two pyridyl-containing crown ethers, (–) or (+)-Xyl-P16C6-Phos, was fabricated and utilized in the Rh-catalyzed asymmetric hydrogenation of α-dehydroamino acid esters and Ir-catalyzed asymmetric hydrogenation of quinolines in high yields...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , , , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2016
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6016442/ https://ncbi.nlm.nih.gov/pubmed/30155106 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00589f |
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