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Ligand Conformational Flexibility Enables Enantioselective Tertiary C–B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration
Conformationally flexible ancillary ligands have been widely used in transition metal catalysis. However, the benefits of using flexible ligands are often not well understood. We performed DFT and experimental studies to elucidate the mechanisms and the roles of conformationally flexible TADDOL-deri...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8324071/ https://ncbi.nlm.nih.gov/pubmed/33750118 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01303 |
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