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Phosphonate-Directed Catalytic Asymmetric Hydroboration: Delivery of Boron to the More Substituted Carbon, Leading to Chiral Tertiary Benzylic Boronic Esters

Phosphonate-directed catalytic asymmetric hydroboration (CAHB) of β-aryl/heteroaryl methylidenes and trisubstituted alkenes by pinacolborane enables facile access to functionalized, chiral tertiary benzylic boronic esters. Hydroboration is catalyzed by a chiral rhodium catalyst prepared in situ from...

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Bibliografische gegevens
Gepubliceerd in:ACS Catal
Hoofdauteurs: Chakrabarty, Suman, Takacs, James M.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2018
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6533611/
https://ncbi.nlm.nih.gov/pubmed/31134137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b03591
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