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Ligand Conformational Flexibility Enables Enantioselective Tertiary C–B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration

Conformationally flexible ancillary ligands have been widely used in transition metal catalysis. However, the benefits of using flexible ligands are often not well understood. We performed DFT and experimental studies to elucidate the mechanisms and the roles of conformationally flexible TADDOL-deri...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Shao, Huiling, Chakrabarty, Suman, Qi, Xiaotian, Takacs, James M., Liu, Peng
Médium: Artigo
Jazyk:Inglês
Vydáno: 2021
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8324071/
https://ncbi.nlm.nih.gov/pubmed/33750118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01303
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