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Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity

Here we highlight past work on metal-dithiolene interactions and how the unique electronic structure of the metal-dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes. The metallodithiolene electronic structures detailed here...

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Detalles Bibliográficos
Publicado en:Inorganics (Basel)
Main Authors: Yang, Jing, Enemark, John H., Kirk, Martin L.
Formato: Artigo
Idioma:Inglês
Publicado: 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8318340/
https://ncbi.nlm.nih.gov/pubmed/34327225
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/inorganics8030019
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