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Vibrational Control of Covalency Effects Related to the Active Sites of Molybdenum Enzymes
A multi-technique spectroscopic and theoretical study of the Cp(2)M(benzenedithiolato) (M=Ti,V,Mo; Cp = η(5)-C(5)H(5)) series provides deep insight into dithiolene electronic structure contributions to electron transfer reactivity and reduction potential modulation in pyranopterin molybdenum enzymes...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7908822/ https://ncbi.nlm.nih.gov/pubmed/30208274 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08254 |
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