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Investigation of metal–dithiolate fold angle effects: Implications for molybdenum and tungsten enzymes

Gas-phase photoelectron spectroscopy and density functional theory have been used to investigate the interactions between the sulfur π-orbitals of arene dithiolates and high-valent transition metals as minimum molecular models of the active site features of pyranopterin Mo/W enzymes. The compounds (...

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Detalhes bibliográficos
Main Authors: Joshi, Hemant K., Cooney, J. Jon A., Inscore, Frank E., Gruhn, Nadine E., Lichtenberger, Dennis L., Enemark, John H.
Formato: Artigo
Idioma:Inglês
Publicado em: The National Academy of Sciences 2003
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC152988/
https://ncbi.nlm.nih.gov/pubmed/12655066
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0636832100
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