Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission

The reactions of terminal acetylenes with doubly Lewis base-stabilised diborenes resulted in different outcomes depending on the nature of the ligands at boron and the conformation of the diborene (cyclic versus acyclic). N-heterocyclic carbene (NHC)-stabilised diborenes tended to undergo anti-selec...

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Vydáno v:Chem Sci
Hlavní autoři: Englert, Lukas, Schmidt, Uwe, Dömling, Michael, Passargus, Max, Stennett, Tom E., Hermann, Alexander, Arrowsmith, Merle, Härterich, Marcel, Müssig, Jonas, Phillipps, Alexandra, Prieschl, Dominic, Rempel, Anna, Rohm, Felix, Radacki, Krzysztof, Schorr, Fabian, Thiess, Torsten, Jiménez-Halla, J. Oscar C., Braunschweig, Holger
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2021
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8314202/
https://ncbi.nlm.nih.gov/pubmed/34349926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc02081a
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