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An effective and versatile strategy for the synthesis of structurally diverse heteroarylsilanes via Ir(iii)-catalyzed C–H silylation

A versatile silylation of heteroaryl C–H bonds is accomplished under the catalysis of a well-defined spirocyclic NHC Ir(iii) complex (SNIr), generating a variety of heteroarylsilanes. A significant advantage of this catalytic system is that multiple types of intermolecular C–H silylation can be achi...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yan, Zhi-Bo, Peng, Meng, Chen, Qi-Long, Lu, Ka, Tu, Yong-Qiang, Dai, Kun-Long, Zhang, Fu-Min, Zhang, Xiao-Ming
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8293992/
https://ncbi.nlm.nih.gov/pubmed/34349947
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc02344f
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