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Overcoming the Naphthyl Requirement in Stereospecific Cross-Couplings to Form Quaternary Stereocenters
The use of a simple stilbene ligand has enabled a stereospecific Suzuki-Miyaura cross-coupling of tertiary benzylic carboxylates, including those lacking naphthyl substituents. This method installs challenging all-carbon, diaryl quaternary stereocenters in good yield and ee, and represents an import...
שמור ב:
| הוצא לאור ב: | J Am Chem Soc |
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| Main Authors: | , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2021
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8255275/ https://ncbi.nlm.nih.gov/pubmed/34062058 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c03898 |
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