A General Approach to Stereospecific Cross-Coupling Reactions of Nitrogen-Containing Stereocenters

A novel strategy employing cyclohexyl spectator ligands in Stille cross-coupling reactions has been developed as a general solution to the long-standing challenge of conducting stereospecific cross-coupling reactions at nitrogen-containing stereocenters. This method enables direct access to enantioe...

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Veröffentlicht in:Chem
Hauptverfasser: Ma, Xinghua, Zhao, Haoran, Binayeva, Meruyert, Ralph, Glenn, Diane, Mohamed, Zhao, Shibin, Wang, Chao-Yuan, Biscoe, Mark R.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2020
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7241476/
https://ncbi.nlm.nih.gov/pubmed/32440572
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chempr.2020.02.002
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