Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion

Bis(1‐(4‐tolyl)‐carboran‐2‐yl)‐(4‐tolyl)‐borane [(1‐(4‐MeC(6)H(4))‐closo‐1,2‐C(2)B(10)H(10)‐2‐)(2)(4‐MeC(6)H(4))B] (1), a new bis(o‐carboranyl)‐(R)‐borane was synthesised by lithiation of the o‐carboranyl precursor and subsequent salt metathesis reaction with (4‐tolyl)BBr(2). Cyclic voltammetry expe...

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Bibliographic Details
Published in:Chemistry
Main Authors: Krebs, Johannes, Haehnel, Martin, Krummenacher, Ivo, Friedrich, Alexandra, Braunschweig, Holger, Finze, Maik, Ji, Lei, Marder, Todd B.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2021
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252506/
https://ncbi.nlm.nih.gov/pubmed/33769625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100938
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