Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence

Using 4‐phenylpyridine or 2‐phenylpyridine in place of biphenyl, two electron‐poor phenylpyridyl‐fused boroles, [TipPBB1](4) and TipPBB2 were prepared. [TipPBB1](4) adopts a unique coordination mode and forms a tetramer with a cavity in both the solid state and solution. The boron center of TipPBB2...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: He, Jiang, Rauch, Florian, Friedrich, Alexandra, Krebs, Johannes, Krummenacher, Ivo, Bertermann, Rüdiger, Nitsch, Jörn, Braunschweig, Holger, Finze, Maik, Marder, Todd B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986225/
https://ncbi.nlm.nih.gov/pubmed/33231909
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013692
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