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Light‐Driven gem Hydrogenation: An Orthogonal Entry into “Second‐Generation” Ruthenium Carbene Catalysts for Olefin Metathesis

The newly discovered light‐driven gem hydrogenation of alkynes opens an unconventional yet efficient entry into five‐coordinate Grubbs‐type ruthenium carbene complexes with cis‐disposed chloride ligands. Representatives of this class featuring a chelate substructure formed by an iodo‐substituted ben...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Zachmann, Raphael J., Fürstner, Alois
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251631/
https://ncbi.nlm.nih.gov/pubmed/33871083
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202101176
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