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Grubbs Metathesis Enabled by a Light‐Driven gem‐Hydrogenation of Internal Alkynes
[(NHC)(cymene)RuCl(2)] (NHC=N‐heterocyclic carbene) complexes instigate a light‐driven gem‐hydrogenation of internal alkynes with concomitant formation of discrete Grubbs‐type ruthenium carbene species. This unorthodox reactivity mode is harnessed in the form of a “hydrogenative metathesis” reaction...
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
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| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
John Wiley and Sons Inc.
2020
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7589215/ https://ncbi.nlm.nih.gov/pubmed/32608043 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007030 |
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